ACS Analytical Chemistry Practice Exam

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In EDTA complexometric titration, what is a masking agent?

A reagent that protects some component of the analyte from reaction with the EDTA

Masking agents in EDTA complexometric titration serve to suppress interference from certain metal ions by binding them so they cannot react with EDTA. This sequestering allows the titration to target the ion of interest without EDTA being consumed by other metals present in the solution. The option describes exactly this protective role—keeping an interfering component from reacting with EDTA—so it best explains the purpose of a masking agent. It isn’t about speeding the reaction with all metals, changing the endpoint color, or increasing solubility of interferents.

A reagent that accelerates the reaction between EDTA and all metal ions

A reagent that alters the color change during the endpoint detection

A reagent that increases the solubility of interfering substances

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